Synthesis of aryl cobalt and iron complexes and their catalytic activity on hydrosilylation of alkenes
Wei Huang, Jiahui Lü, Qingqing Fan, Xiaoyan Li, Alexander Hinz, Hongjian Sun
Abstract
Four aryl Co and Fe complexes, (F 4 C 5 N)CoCl(PMe 3 ) 3 (1), (F 4 C 5 N)Fe(PMe 3 ) 4 (2), (F 5 C 6 )CoCl(PMe 3 ) 3 (3) and (F 4 C 5 )FeCl(PMe 3 ) 3 (4), were synthesized from the reactions of 3-chloro-2,4,5,6-tetrafluoro-pyridine and chloropentafluorobenzene with Co(PMe 3 ) 4 and Fe(PMe 3 ) 4 , respectively.
Topics & Concepts
ChemistryArylCobaltHydrosilylationCatalysisPyridineMedicinal chemistryOrganic chemistryAlkylOrganoboron and organosilicon chemistryCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization Methods