New class of RSO<sub>2</sub>-NHC ligands and Pd/RSO<sub>2</sub>-NHC complexes with tailored electronic properties and high performance in catalytic C–C and C–N bonds formation
Dmitry V. Pasyukov, М. А. Шевченко, Alexander V. Astakhov, Mikhail E. Minyaev, Yu Zhang, Victor M. Chernyshev, Valentine P. Ananikov
Abstract
-functionalized imidazolium salts under mild conditions. Several complexes demonstrated good activity in the catalysis of model cross-coupling reactions, outperforming the activity of similar complexes with non-substituted NHC ligands.
Topics & Concepts
CatalysisLigand (biochemistry)ChemistryClass (philosophy)Core (optical fiber)StereochemistryMedicinal chemistryMaterials scienceOrganic chemistryComputer scienceReceptorArtificial intelligenceComposite materialBiochemistryN-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization Methods