Photochemical and electrochemical C–N borylation of arylhydrazines
Linlin Du, Li Sun, Hua Zhang
Abstract
The C-N borylation of arylhydrazine hydrochlorides with bis(pinacolato)diboron was achieved under photochemical and electrochemical conditions, respectively. This novel and scalable transformation provides two efficient and mild transition-metal-free synthetic routes towards aryl boronate esters from easily available arylhydrazines.
Topics & Concepts
BorylationChemistryElectrochemistryArylCombinatorial chemistryPhotochemistryOrganic chemistryElectrodeAlkylPhysical chemistryRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques