Ferroelectricity in Atomic Layer Deposited Wurtzite Zinc Magnesium Oxide Zn<sub>1–<i>x</i></sub>Mg<sub><i>x</i></sub>O
Benjamin L. Aronson, Kyle P. Kelley, Ece Gunay, Ian P. Mercer, Bogdan Dryzhakov, Jon‐Paul Maria, Elizabeth C. Dickey, Susan Trolier‐McKinstry, Jon F. Ihlefeld
Abstract
High Resolution Image Download MS PowerPoint Slide Conformal deposition of wurtzite ferroelectrics, which is needed for their use in scaled nonvolatile memories, is challenging using current physical vapor deposition techniques. To overcome the conformality barrier, this work demonstrates ferroelectricity in wurtzite Zn 1– x Mg x O thin films prepared by plasma-enhanced atomic layer deposition, which is a non-line-of-sight deposition method. Films ranging in composition from x = 0.00 to x = 0.58 are predominantly wurtzite phase and exhibit a (0001)-texture. Increasing the magnesium content decreases the c / a ratio, increases the optical bandgap energy, increases the piezoelectric response, and enables polarization reversal. Clear polarization switching is demonstrated in 50 nm thick Zn 1– x Mg x O films by piezoresponse force microscopy in compositions containing x = 0.46 and x = 0.58.