Litcius/Paper detail

A new photochromic Gd-MOF with photoswitchable bluish-white to greenish-yellow emission based on electron transfer

Pei-Xin Li, Zhi-Xin Xie, Ai-Ping Jin, Jing Li, Guo‐Cong Guo

2020Chemical Communications46 citationsDOI

Abstract

Utilization of photochromism in photo-switchable white-light emitters (WLEs) is a challenging task. In an effort to achieve this, we have recently developed a new Gd-MOF using a photoactive pyridinium-based inner salt. The compound shows interesting photoswitchable bluish white light to greenish yellow light emission as a result of electron transfer, a phenomenon that has not been observed previously in photochromic crystal compounds.

Topics & Concepts

PhotochromismPhotochemistryElectronElectron transferWhite lightMaterials scienceChemistryOptoelectronicsPhysicsQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsNanoplatforms for cancer theranosticsLuminescence Properties of Advanced Materials