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Cooperative dihydrogen activation with unsupported uranium–metal bonds and characterization of a terminal U(<scp>iv</scp>) hydride

Robert J. Ward, Pokpong Rungthanaphatsophon, Patrick Huang, Steven P. Kelley, Justin R. Walensky

2023Chemical Science18 citationsDOIOpen Access PDF

Abstract

(MesO)U(H)]. All complexes have been characterized by spectroscopic and structural methods and are rare examples of cooperative chemistry in f element chemistry, dihydrogen activation, and stable, terminal ethyl and hydride compounds with an f element.

Topics & Concepts

UraniumHydrideChemistryTerminal (telecommunication)Characterization (materials science)MetalInorganic chemistryMaterials scienceMetallurgyOrganic chemistryNanotechnologyComputer scienceTelecommunicationsChemical Reactions and IsotopesAsymmetric Hydrogenation and CatalysisCoordination Chemistry and Organometallics