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Expanding the Medicinal Chemist Toolbox: Comparing Seven C(sp<sup>2</sup>)–C(sp<sup>3</sup>) Cross-Coupling Methods by Library Synthesis

Amanda W. Dombrowski, Nathan J. Gesmundo, Ana L. Aguirre, Katerina A. Sarris, Jonathon M. Young, Andrew R. Bogdan, M. Cynthia Martin, Shasline Gedeon, Ying Wang

2020ACS Medicinal Chemistry Letters234 citationsDOIOpen Access PDF

Abstract

) coupling methods, like tertiary group installation. The results reported herein should be used to inform future syntheses, assess reaction scope, and encourage medicinal chemists to expand their synthetic toolbox.

Topics & Concepts

ToolboxScope (computer science)ChemistComputer scienceCombinatorial chemistryArylCoupling (piping)ChemistryDrug discoveryAlkylOrganic chemistryEngineeringProgramming languageBiochemistryMechanical engineeringCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsAsymmetric Hydrogenation and Catalysis
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