The influence of depropagation on PEGMA<sub>9</sub> solution radical homopolymerization and copolymerization with DEAEMA: <i>in situ</i><sup>1</sup>H-NMR measurements and reactivity ratio estimation by dynamic optimization
Judith Cabello-Romero, José R. Torres‐Lubián, Francisco Javier Enríquez‐Medrano, Robin A. Hutchinson, Iván Zapata‐González
Abstract
The concentration affects the depropagation–propagation equilibrium of PEGMA 9 due to the backbone flexibility, but this effect on its copolymerization with DEAEMA is negligible.
Topics & Concepts
CopolymerReactivity (psychology)ChemistryFlexibility (engineering)Polymer chemistryOrganic chemistryPolymerMedicineAlternative medicineStatisticsMathematicsPathologyAdvanced Polymer Synthesis and CharacterizationLanthanide and Transition Metal ComplexesPolymer Surface Interaction Studies