Fluorescent Metallosupramolecular Elastomers for Fast and Ultrasensitive Humidity Sensing
Miaomiao Li, Quanqian Lyu, Lvetao Sun, Bolun Peng, Lianbin Zhang, Jintao Zhu
Abstract
Fluorescent supramolecular polymers that can respond to subtle external stimuli to generate luminescence signals are promising in a wide range of applications, including probes, anti-counterfeiting materials, and sensors. However, complicated preparative procedures, limited responsive speed, and relatively low sensitivity still limit their practical sensing applications. Herein, we report europium-containing metallosupramolecular (PU-Eu) elastomers for fast and ultrasensitive humidity sensing by employing hygroscopic polyurethane (PU), whose urethane groups can coordinate with europium ions (Eu3+), emitting a strong luminescent signal by ligand-to-metal energy transfer. The variant of the coordination bond strength triggered by external humidity imparts the PU-Eu elastomer with a fast (∼1.1 s) and ultrasensitive response to the humid condition, where the external humidity increases by ∼1% and the corresponding fluorescence intensity will drop by ∼421.98 a.u. By a dip-coating process, PU-Eu elastomers can be conveniently coated on a hydrophilic and porous cellulose acetate nanofiber membrane, and the resulting composite membrane can achieve real-time and reversible monitoring of environmental humidity and human respiration. Given the versatility of PU-Eu elastomers, this study provides a low-cost and facile route of obtaining fluorescent metallosupramolecular polymers for fast and ultrasensitive humidity sensing.