Self-Standing MOF-Derived Co@SiC<sub>nw</sub> Nanocomposite Aerogel with a Hierarchical Microstructure for Highly Effective and Wideband Electromagnetic Attenuation
Yi Hou, Ji‐Xiang Wang, Baijun Chen, Hui Zhang, Zichen Xiang, Haikui Zhu, Lixi Wang
Abstract
To meet the requirements of lightweight and wideband attenuation for advanced electromagnetic (EM) absorption materials, the combination of both MOF composition and hierarchical structural design was applied as the strategy to prepare the MOF-derived Co@SiC nanowire (Co@SiC nw ) nanocomposite aerogel. The hierarchical and laminated structures with multiple Co@SiC nw layers were constructed via a mixed growth-assisted freeze-drying and calcination process. The ultralightweight Co@SiC nw presents a low density of 0.11 g/cm 3 . With abundant second-phase polarization interfaces and enlarged EM wave attenuation channels to enhance dielectric and conductive loss, the optimized Co@SiC nw offers a minimal reflection loss (RL min ) of −61.4 dB at 10.0 GHz (2.64 mm) and an effective absorption bandwidth (EAB) as wide as 7.44 GHz with a sample thickness of only 2.16 mm. Furthermore, multifunctionalities, including low density, thermal insulation, and self-standing, were demonstrated for Co@SiC nw, making it a high-performance and practical microwave absorption material.