Understanding High‐Rate K<sup>+</sup>‐Solvent Co‐Intercalation in Natural Graphite for Potassium‐Ion Batteries
Lin Li, Luojia Liu, Zhe Hu, Yong Lü, Qiannan Liu, Song Jin, Qiu Zhang, Shuo Zhao, Shulei Chou
Abstract
Abstract Graphite shows great potential as an anode material for rechargeable metal‐ion batteries because of its high abundance and low cost. However, the electrochemical performance of graphite anode materials for rechargeable potassium‐ion batteries needs to be further improved. Reported herein is a natural graphite with superior rate performance and cycling stability obtained through a unique K + ‐solvent co‐intercalation mechanism in a 1 m KCF 3 SO 3 diethylene glycol dimethyl ether electrolyte. The co‐intercalation mechanism was demonstrated by ex situ Fourier transform infrared spectroscopy and in situ X‐ray diffraction. Moreover, the structure of the [K‐solvent] + complexes intercalated with the graphite and the conditions for reversible K + ‐solvent co‐intercalation into graphite are proposed based on the experimental results and first‐principles calculations. This work provides important insights into the design of natural graphite for high‐performance rechargeable potassium‐ion batteries.