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Please Avoid Plotting Analytical Response against Logarithm of Concentration

Pawel L. Urban

2020Analytical Chemistry37 citationsDOI

Abstract

This perspective highlights a malpractice in handling calibration data sets. It refers to relating analytical response with logarithm of concentration, fitting such a data set with linear function, and deriving method characteristics from the slope of that function. A distinction is made between this malpractice and the proper use of logarithmic plots in representation of calibration data sets.

Topics & Concepts

LogarithmCalibrationRepresentation (politics)Function (biology)Set (abstract data type)ChemistryData setApplied mathematicsPerspective (graphical)StatisticsMathematicsMathematical analysisComputer scienceArtificial intelligenceLawBiologyPolitical scienceProgramming languagePoliticsEvolutionary biologyPesticide Residue Analysis and SafetySpectroscopy and Chemometric AnalysesScientific Measurement and Uncertainty Evaluation
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