Boosting the reduction of CO<sub>2</sub> and dimethylamine for C–N bonding to synthesize DMF <i>via</i> modulating the electronic structures of indium single atoms
Jingui Zheng, Shaohan Xu, Lingzhi Sun, Xun Pan, Qihao Xie, Guohua Zhao
Abstract
The indium single atom of InN 3 affects the electronic properties of adsorption of CO 2 and HN(CH 3 ) 2 . This resulted in hydrogen transfer from HN(CH 3 ) 2 to CO 2 , generating the intermediate species of *N(CH 3 ) 2 and *COOH that are conducive to C–N coupling.
Topics & Concepts
DimethylamineIndiumBoosting (machine learning)Reduction (mathematics)Materials scienceChemistryNanotechnologyCrystallographyOptoelectronicsComputer scienceOrganic chemistryMathematicsGeometryMachine learningCarbon dioxide utilization in catalysisAmmonia Synthesis and Nitrogen ReductionCO2 Reduction Techniques and Catalysts