Chemical control of competing electron transfer pathways in iron tetracyano-polypyridyl photosensitizers
Kristjan Kunnus, Lin Li, Charles J. Titus, Sang‐Jun Lee, Marco Reinhard, Sergey Koroidov, Kasper S. Kjær, Kiryong Hong, Kathryn Ledbetter, W. B. Doriese, G. C. O’Neil, Daniel S. Swetz, Joel N. Ullom, Dale Li, K. D. Irwin, Dennis Nordlund, Amy A. Cordones, Kelly J. Gaffney
Abstract
Photoinduced intramolecular electron transfer in Fe tetracyano-polypyridyl complexes was investigated with static and time-resolved UV-visible absorption and resonant inelastic X-ray scattering which revealed a competition of two relaxation pathways.
Topics & Concepts
Intramolecular forceElectron transferPhotochemistryChemistryElectron exchangeAbsorption (acoustics)Relaxation (psychology)ElectronMaterials sciencePhysicsStereochemistryOrganic chemistryComposite materialSocial psychologyQuantum mechanicsPsychologyIonPhotochemistry and Electron Transfer StudiesAdvanced Chemical Physics StudiesElectrocatalysts for Energy Conversion