Electrochemical oxidative dehydrogenation of hydrosilanes to generate silyl radicals: an efficient method for the construction of Si–O/Si–Si bonds utilizing a recyclable ionic liquid catalyst
Zhaoxin Wei, Ziren Chen, Fei Xue, Yuancheng Yue, Shaofeng Wu, Yonghong Zhang, Bin Wang, Yu Xia, Weiwei Jin, Chenjiang Liu
Abstract
A highly efficient and sustainable approach was developed for the construction of Si–O/Si–Si bonds, through the electrochemical oxidative dehydrogenation of hydrosilanes with O -nucleophiles or self-condensation of hydrosilanes.
Topics & Concepts
DehydrogenationSilylationIonic liquidCatalysisElectrochemistryRadicalChemistryOxidative phosphorylationIonic bondingInorganic chemistryPolymer chemistryOrganic chemistryIonElectrodePhysical chemistryBiochemistryRadical Photochemical ReactionsAmmonia Synthesis and Nitrogen ReductionChemical Synthesis and Reactions