Litcius/Paper detail

Exfoliated g-C<sub>3</sub>N<sub>4</sub> as efficient sorbent for Pb ions removal from synthetic wastewaters

A. Modwi

2023Zeitschrift für Naturforschung A10 citationsDOI

Abstract

Abstract A successful exfoliation of g-C 3 N 4 was achieved via ultrasonic power and ethanol as a solvent. The untreated (CN1) and treated (CN2) samples were characterized using various techniques. The X-ray diffraction (XRD) ascertained the formation of a typical nitride entity with less intense peaks for the ultra-sonicated sample. The FTIR, EDX, and XPS data have jointly confirmed the formation of the target compound. By virtue of its enhanced BET surface area (277 m 2 g −1 ) the treated samples could effectively adsorb 278 mg g −1 of Pb (II) in a considerably short time of 47 min. The adsorption phenomenon was found to abide with the second ‵ order kinetics and adopt a Langmuir isotherm behavior. Lead (II) elimination showed high removal efficiency after up to four cycles of effective recycling. This study demonstrated that CN2 nanosheets might be approved as an effective and stable candidate for eliminating dangerous heavy metal pollutants.

Topics & Concepts

Exfoliation jointAdsorptionSorbentX-ray photoelectron spectroscopyLangmuir adsorption modelNuclear chemistryMetal ions in aqueous solutionMetalSonicationSolventKineticsFourier transform infrared spectroscopyNitrideMaterials scienceAqueous solutionChemistryBET theoryChemical engineeringChromatographyNanotechnologyLayer (electronics)Physical chemistryOrganic chemistryPhysicsQuantum mechanicsGrapheneEngineeringAdvanced Photocatalysis TechniquesMXene and MAX Phase MaterialsGas Sensing Nanomaterials and Sensors