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Unprecedented boat-shaped [Mo<sub>2</sub>O<sub>5</sub>(IO<sub>3</sub>)<sub>4</sub>]<sup>2−</sup> polyanions induced a strong second harmonic generation response

Wei‐Cai Zeng, Xuehua Dong, Yao Tian, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

2022Chemical Communications30 citationsDOI

Abstract

The first organic–inorganic hybrid guanidine molybdenyl iodate [C(NH 2 ) 3 ] 2 Mo 2 O 5 (IO 3 ) 4 ·2H 2 O features unprecedented boat-shaped [Mo 2 O 5 (IO 3 ) 4 ] 2− polyanion clusters, which induce a strong second harmonic generation response.

Topics & Concepts

IodateHydrothermal circulationSecond-harmonic generationNonlinear opticalCluster (spacecraft)BirefringenceCrystallographyHarmonicHydrothermal synthesisBand gapChemistryMaterials scienceAnalytical Chemistry (journal)Inorganic chemistryPhysicsNonlinear systemOptoelectronicsOpticsChemical engineeringOrganic chemistryIodideComputer scienceLaserQuantum mechanicsEngineeringProgramming languageCrystal Structures and PropertiesNonlinear Optical Materials ResearchPorphyrin and Phthalocyanine Chemistry
Unprecedented boat-shaped [Mo<sub>2</sub>O<sub>5</sub>(IO<sub>3</sub>)<sub>4</sub>]<sup>2−</sup> polyanions induced a strong second harmonic generation response | Litcius