Room-temperature sub-100 nm Néel-type skyrmions in non-stoichiometric van der Waals ferromagnet Fe3-xGaTe2 with ultrafast laser writability
Zefang Li, Huai Zhang, Guanqi Li, Jiangteng Guo, Qingping Wang, Ying Deng, Yue Hu, Xuange Hu, Can Liu, Minghui Qin, Xi Shen, Richeng Yu, Xingsen Gao, Zhi‐Min Liao, Jun‐Ming Liu, Zhipeng Hou, Yimei Zhu, Xuewen Fu
Abstract
Abstract Realizing room-temperature magnetic skyrmions in two-dimensional van der Waals ferromagnets offers unparalleled prospects for future spintronic applications. However, due to the intrinsic spin fluctuations that suppress atomic long-range magnetic order and the inherent inversion crystal symmetry that excludes the presence of the Dzyaloshinskii-Moriya interaction, achieving room-temperature skyrmions in 2D magnets remains a formidable challenge. In this study, we target room-temperature 2D magnet Fe 3 GaTe 2 and unveil that the introduction of iron-deficient into this compound enables spatial inversion symmetry breaking, thus inducing a significant Dzyaloshinskii-Moriya interaction that brings about room-temperature Néel-type skyrmions with unprecedentedly small size. To further enhance the practical applications of this finding, we employ a homemade in-situ optical Lorentz transmission electron microscopy to demonstrate ultrafast writing of skyrmions in Fe 3- x GaTe 2 using a single femtosecond laser pulse. Our results manifest the Fe 3- x GaTe 2 as a promising building block for realizing skyrmion-based magneto-optical functionalities.