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Copper-catalyzed regio- and chemoselective selenosulfonylation of 1,6-enynes from sulfur dioxide

Fu‐Sheng He, Yanfang Yao, Zhimei Tang, Wenlin Xie, Jie Wu

2021Organic Chemistry Frontiers35 citationsDOI

Abstract

An efficient copper-catalyzed multicomponent reaction of 1,6-enynes, diselenides, DABCO·(SO 2 ) 2 , and cycloketone oxime esters was achieved, providing cyanoalkylsulfonated pyrrolidines in moderate to good yields.

Topics & Concepts

ChemistryDABCOCopperCatalysisOximeSulfur dioxideSulfurOrganic chemistryReaction conditionsCombinatorial chemistrySulfur-Based Synthesis TechniquesOrganoselenium and organotellurium chemistryChemical Synthesis and Reactions
Copper-catalyzed regio- and chemoselective selenosulfonylation of 1,6-enynes from sulfur dioxide | Litcius