BaSc<sub>2</sub>(HPO<sub>3</sub>)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>: a new nonlinear optical phosphite exhibiting a 3D {[Sc<sub>2</sub>(HPO<sub>3</sub>)<sub>4</sub>]<sup>2−</sup>}<sub>∞</sub> anionic framework and phase-matchable SHG effect
Ru‐Ling Tang, Gang-Xiang Liu, Wen‐Dong Yao, Li-Nan Zhang, Wenlong Liu, Sheng‐Ping Guo
Abstract
The first barium scandium phosphite, BaSc 2 (HPO 3 ) 4 (H 2 O) 2 , has been systematically studied. It exhibits a 3D [Sc 2 (HPO 3 ) 4 ] 2− anion framework with an SHG effect (0.94 × KDP) and phase-matching behaviour.
Topics & Concepts
ScandiumBariumIonChemistryAnalytical Chemistry (journal)Phase (matter)Inorganic chemistryPhysical chemistryCrystallographyMaterials scienceOrganic chemistryCrystal Structures and PropertiesChemical Synthesis and CharacterizationZeolite Catalysis and Synthesis