Scandium, titanium and vanadium complexes supported by PCP-type pincer ligands: synthesis, structure, and styrene polymerization activity
Jiayu Zhang, Wenshuang Huang, Kailing Han, Guoyong Song, Shaowei Hu
Abstract
) polymerization of styrene. Meanwhile, the Ti(III) complexes 1-Ti and 2-Ti showed rather low activity in styrene polymerization, which stands in sharp contrast to those in previous reports involving Ti(III) catalysts bearing cyclopentadienyl derivative ligands.
Topics & Concepts
StyrenePincer movementPolymerizationScandiumCyclopentadienyl complexChemistryVanadiumPolymer chemistryTransition metalSubstituentCrystallographyCatalysisStereochemistryInorganic chemistryOrganic chemistryPolymerCopolymerOrganometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysisOrganoboron and organosilicon chemistry