X-type silyl ligands for transition-metal catalysis
Jihui Gao, Yicong Ge, Chuan He
Abstract
-effects of silyl ligands, highlighting their crucial roles in enhancing the reactivity and selectivity of various catalytic reactions, including small molecule activation, Kumada cross-coupling, hydrofunctionalization, C-H functionalization, and dehydrogenative Si-O coupling reactions. Additionally, future developments in this field are also provided, which would inspire new insights and applications in catalytic synthetic chemistry.
Topics & Concepts
SilylationTransition metalCatalysisChemistryMetalCombinatorial chemistryOrganic chemistryAsymmetric Hydrogenation and CatalysisCatalytic Cross-Coupling ReactionsCarbon dioxide utilization in catalysis