Fe<sub>3</sub>O<sub>4</sub>@GlcA@Cu-MOF: A Magnetic Metal–Organic Framework as a Recoverable Catalyst for the Hydration of Nitriles and Reduction of Isothiocyanates, Isocyanates, and Isocyanides
Arash Ghorbani‐Choghamarani, Zahra Taherinia
Abstract
A novel magnetic metal–organic framework (Fe3O4@GlcA@Cu-MOF) has been prepared and characterized by spectroscopic, microscopic, and magnetic techniques. This magnetically separable catalyst exhibited high catalytic activity for nitrile hydration and the ability to reduce isothiocyanates, isocyanates, and isocyanides with excellent activity and selectivity without any additional reducing agent.
Topics & Concepts
ChemistryNitrileCatalysisMetal-organic frameworkMetalSelectivityReducing agentInorganic chemistryOrganic chemistryAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and ReactionsSulfur-Based Synthesis Techniques