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Benzosuberyl installed “sandwich” type unsymmetrical α-diimine nickel precatalysts for synthesizing plastomeric to elastomeric polyethylene

Aibo Zhou, Rongyan Yuan, Qaiser Mahmood, Shifang Yuan, Yizhou Wang, Zexu Hu, Song Zou, Tongling Liang, Wen‐Hua Sun

2024Polymer Chemistry24 citationsDOI

Abstract

In the present study, with the incorporation of 2,4,6-tris(5-dibenzosuberyl)aniline, a new family of “sandwich” type unsymmetrical α-diimine-nickel precatalysts was prepared for the synthesis of plastomeric to elastomeric polyethylene.

Topics & Concepts

DiimineElastomerPolyethyleneNickelPolymer chemistryMaterials scienceComposite materialCatalysisChemistryOrganic chemistryMetallurgyOrganometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysisCatalysis and Oxidation Reactions