Enantioselective reductive allylic alkylation enabled by dual photoredox/palladium catalysis
Sheng Tang, Hong‐Hao Zhang, Shouyun Yu
Abstract
) bonds under mild reaction conditions. Mechanistic studies suggest that this reaction involves radical pathways and a chiral Pd complex enables the control of the regio- and enantioselectivities.
Topics & Concepts
PalladiumTsuji–Trost reactionEnantioselective synthesisAlkylationCatalysisCombinatorial chemistryChemistryAllylic rearrangementDual (grammatical number)Organic chemistryLiteratureArtRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions