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Adaptive Catalytic Systems for Chemical Energy Conversion

Alexis Bordet, Walter Leitner

2023Angewandte Chemie International Edition48 citationsDOIOpen Access PDF

Abstract

Abstract The rapidly growing importance of green hydrogen and renewable carbon resources as essential feedstocks for sustainable chemical value chains opens room for disruptive innovations regarding chemical production processes. The fluctuation and variability associated with non‐fossil energy and raw material supply holds many challenges for catalysts to cope with the resulting dynamics. However, many new opportunities also arise once catalyst design starts to aim at performance that is “adaptive” rather than “task‐specific”. In this Scientific Perspective, we propose to define adaptivity in catalysis on the basis of three essential properties that are reversibility, rapidity, and robustness ( R 3 rule). Promising design strategies and selected examples are described to substantiate the scientific concept and to highlight its potential for chemical energy conversion.

Topics & Concepts

Biochemical engineeringRenewable energyRobustness (evolution)Raw materialChemical processCatalysisFossil fuelChemical energyComputer scienceEnvironmental economicsProcess engineeringNanotechnologyChemistryMaterials scienceEngineeringEconomicsChemical engineeringWaste managementElectrical engineeringBiochemistryOrganic chemistryGeneCatalysis and Hydrodesulfurization StudiesElectrocatalysts for Energy ConversionAsymmetric Hydrogenation and Catalysis