Hydrogen-atom and oxygen-atom transfer reactivities of iron(<scp>iv</scp>)-oxo complexes of quinoline-substituted pentadentate ligands
Sandip Munshi, Arup Sinha, Solomon Yiga, Sridhar Banerjee, Reena Singh, Md. Kamal Hossain, Matti Haukka, Andrei Felipe Valiati, Ricardo Dagnoni Huelsmann, Edmar Martendal, Rosely A. Peralta, Fernando R. Xavier, Ola F. Wendt, Tapan Kanti Paine, Ebbe Nordlander
Abstract
is also manifested in higher HAT and OAT rates relative to the other reported complexes of ligands based on the N4Py framework. The results reported here confirm that the steric influence of the ligand environment is of critical importance for the reactivity of iron(IV)-oxo complexes, but additional electronic factors must influence the reactivity of iron-oxo complexes of N4Py derivatives.
Topics & Concepts
ChemistryAcetonitrileSteric effectsLigand (biochemistry)QuinolineCrystallographyMoietyStereochemistryMedicinal chemistryPhotochemistryOrganic chemistryReceptorBiochemistryMetal-Catalyzed Oxygenation MechanismsMagnetism in coordination complexesMetal complexes synthesis and properties