Bioinspired motifs in proton and CO₂ reduction with 3d-metal polypyridine complexes

Abstract

intramolecular routes. The selected exemplars have been chosen to emphasize that, although the molecular structures and the synthetic motifs are different from those of the active sites of natural enzymes, many affinities in terms of catalytic mechanism and functionality are instead present, which account for the observed remarkable performances under operative conditions. The data discussed herein thus demonstrate the great potential and the privileged role of molecular catalysts towards the design and construction of hybrid photochemical systems for solar energy conversion into fuels.

Topics & Concepts