DFT-based microkinetic model analysis of dry reforming of methane over Ru<sub>7</sub>/CeO<sub>2</sub>(111) and Ru<sub>7</sub>/CeO<sub>2</sub>(110): key role of surface lattice oxygen vacancy
Pengfei Qu, Gui‐Chang Wang
Abstract
Surface oxygen vacancies play a crucial role in the step of CO 2 activation, and DRM activity on the CeO 2 (110) facet is higher than that on the CeO 2 (111) facet-supported Ru cluster.
Topics & Concepts
Facet (psychology)CatalysisCluster (spacecraft)MethaneOxygenChemistryMaterials scienceComputer scienceBiochemistrySocial psychologyPersonalityPsychologyBig Five personality traitsOrganic chemistryProgramming languageCatalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions