Influence of perhalophenyl groups in the TADF mechanism of diphosphino gold(<scp>i</scp>) complexes
Inés Soldevilla, Aimara García‐Camacho, Rinat T. Nasibullin, M. Elena Olmos, Miguel Monge, Dage Sundholm, Rashid R. Valiev, José M. López‐de‐Luzuriaga, María Rodríguez‐Castillo
Abstract
Four new perhalophenylgold( i )–diphosphino complexes have been described as TADF emitters. The position and the electronegativity of the halogen atoms in the aromatic ring allow tuning of the photophysical properties.
Topics & Concepts
ElectronegativityMaterials scienceHalogenRing (chemistry)Mechanism (biology)CrystallographyPhotochemistryOrganic chemistryChemistryPhysicsQuantum mechanicsAlkylOrganic Light-Emitting Diodes ResearchOrganometallic Complex Synthesis and CatalysisMetal complexes synthesis and properties