A Universal Lab‐on‐Salt‐Particle Approach to 2D Single‐Layer Ordered Mesoporous Materials
Yi Liu, Xuanyu Yang, Yujie Xie, Huan Liu, Xinran Zhou, Xingyu Xiao, Yuan Ren, Zhen Ma, Xiaowei Cheng, Yonghui Deng, Dongyuan Zhao
Abstract
Abstract The advantages of existing ordered mesoporous materials have not yet been fully realized, due to their limited accessibility of in‐pore surface and long mass‐diffusion length. A general, controllable, and scalable synthesis of a family of two‐dimensional (2D) single‐layer ordered mesoporous materials (SOMMs) with completely exposed mesopore channels, significantly improved mass diffusion, and diverse framework composition is reported here. The SOMMs are synthesized via a surface‐limited cooperative assembly (SLCA) on water‐removable substrates of inorganic salts (e.g., NaCl), combined with vacuum filtration. As a proof of concept, the obtained CeO 2 ‐based SOMMs show superior catalytic performance in CO oxidation with high conversion efficiency, ≈33 times higher than that of conventional bulk mesoporous CeO 2 . This SLCA is a promising approach for developing next‐generation porous materials for various applications.