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Metal‐Based Multihelicenic Architectures

Etienne S. Gauthier, Rafael Rodríguez, Jeanne Crassous

2020Angewandte Chemie International Edition60 citationsDOIOpen Access PDF

Abstract

The preparation of multihelicenic systems by conventional organic synthesis is a challenging task and under continuous development. In parallel, using complexing units grafted to or incorporated within the helicene core and taking advantage of coordination/organometallic chemistry constitutes a powerful strategy to obtain multihelicenic structures. This Minireview focuses on the state-of-the-art preparation of metal-based multihelicenic architectures such as coordination-driven supramolecular assemblies and organometallic architectures. Their properties and their applications are presented.

Topics & Concepts

Supramolecular chemistryNanotechnologyHeliceneCoordination complexGroup 2 organometallic chemistryMetal-organic frameworkChemistryOrganometallic chemistryMetalCombinatorial chemistryMaterials scienceMoleculeOrganic chemistryCatalysisAdsorptionSynthesis and Properties of Aromatic CompoundsLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials
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