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Non-volatile electrical polarization switching via domain wall release in 3R-MoS2 bilayer

Dongyang Yang, Jing Liang, Jingda Wu, Yunhuan Xiao, Jerry I. Dadap, Kenji Watanabe, Takashi Taniguchi, Ziliang Ye

2024Nature Communications51 citationsDOIOpen Access PDF

Abstract

Abstract Understanding the nature of sliding ferroelectricity is of fundamental importance for the discovery and application of two-dimensional ferroelectric materials. In this work, we investigate the phenomenon of switchable polarization in a bilayer MoS 2 with natural rhombohedral stacking, where the spontaneous polarization is coupled with excitonic effects through asymmetric interlayer coupling. Using optical spectroscopy and imaging techniques, we observe how a released domain wall switches the polarization of a large single domain. Our results highlight the importance of domain walls in the polarization switching of non-twisted rhombohedral transition metal dichalcogenides and open new opportunities for the non-volatile control of their optical response.

Topics & Concepts

FerroelectricityPolarization (electrochemistry)StackingMaterials scienceBilayerTrigonal crystal systemOptoelectronicsInduced polarizationOptical switchChemical physicsCondensed matter physicsNanotechnologyChemistryCrystallographyMembraneNuclear magnetic resonancePhysicsDielectricElectrical resistivity and conductivityCrystal structureQuantum mechanicsPhysical chemistryBiochemistry2D Materials and ApplicationsPerovskite Materials and ApplicationsAdvanced Sensor and Energy Harvesting Materials
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