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Effects of Long-Term CO<sub>2</sub> Storage on Carbonate Rock Stability

Hani Al-Mukainah, Abdulameer Almalichy, Mohamed Mahmoud, Murtada Saleh Aljawad, Ahmed Farid Ibrahim, Mustafa Al Ramadan, Ahmed Al‐Yaseri

2025Energy & Fuels10 citationsDOI

Abstract

Carbon geostorage (CGS) is a proven technique for reducing anthropogenic CO 2 emissions and mitigating global warming by injecting CO 2 into deep geologic formations like saline aquifers or reservoirs. However, long-term exposure to CO 2 -rich brine can alter the petrophysical properties and impact the storage integrity. This study examines the impact of CO 2 sequestration on the limestone core sample integrity, focusing on porosity, wormhole formation, and geometric tortuosity. Four limestone samples of 1.5-in. in diameter and 3-in. in length were aged in live brine at 60 °C and 2000 psi for 60 days to simulate sequestration conditions. Results showed a uniform increase in porosity, minimal wormhole formation with negligible impact on rock integrity, and increased geometric tortuosity, adding pathway complexity without compromising structural stability. These findings confirm limestone’s suitability for long-term CO 2 storage.

Topics & Concepts

CarbonateTerm (time)GeologyStability (learning theory)MineralogyGeochemistryEnvironmental scienceMaterials scienceMetallurgyComputer scienceQuantum mechanicsPhysicsMachine learningCO2 Sequestration and Geologic InteractionsMethane Hydrates and Related PhenomenaHydrocarbon exploration and reservoir analysis
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