Chiral <i>N</i>‐<i>tert</i>‐Butylsulfinyl Imines: New Discoveries
Francisco Foubelo, Miguel Yus
Abstract
In this account the reactions of chiral N-tert-butylsulfinyl imines with organometallic reagents such as organoalkaline (lithium, sodium, potassium and cesium derivatives), organomagnesium, organozinc, organoboron, organoaluminium, organoindium and organosilicon compounds is comprehensively described. The reactivity in all cases is derived to synthetic applications in order to prepare interesting organic nitrogenated molecules, especially in the field of alkaloid compounds.
Topics & Concepts
OrganosiliconReactivity (psychology)ReagentChemistryLithium (medication)PotassiumOrganic chemistryGroup 2 organometallic chemistryAlkaloidCombinatorial chemistryMoleculePathologyMedicineAlternative medicineEndocrinologyAsymmetric Synthesis and CatalysisAdvanced Synthetic Organic ChemistryAsymmetric Hydrogenation and Catalysis