Triplet quenching pathway control with molecular dyads enables the identification of a highly oxidizing annihilator class
Maria‐Sophie Bertrams, Katharina Hermainski, Jean-Marc Mörsdorf, Joachim Ballmann, Christoph Kerzig
Abstract
Molecular dyads efficiently transfer the triplet energy, whereas the parent metal complexes and organic photosensitizers reduce these substrates, leading to the identification of unexplored triplet photochemistry and novel aqueous annihilators.
Topics & Concepts
ChemistryPhotochemistryQuenching (fluorescence)Flash photolysisIntersystem crossingRutheniumSinglet stateOxidizing agentPyreneAcceptorTriplet stateExcited stateMoleculeFluorescenceOrganic chemistryPhysicsCondensed matter physicsQuantum mechanicsNuclear physicsReaction rate constantKineticsCatalysisLuminescence and Fluorescent MaterialsRadical Photochemical ReactionsFluorine in Organic Chemistry