Arylgermylation of alkenes by a cooperative photoactivation and hydrogen atom transfer strategy
Jia Cao, Yan Liu, Zhixiang Wang, Le Liu
Abstract
An efficient photoredox/HAT dual-catalysed arylgermylation of alkenes using readily available alkenes, germyl hydrides and (hetero)aryl nitriles, providing a variety of high-functionality germanium-containing molecules with quaternary carbons.
Topics & Concepts
ChemistryHydrogen atomPhotochemistryAtom (system on chip)HydrogenOrganic chemistryGroup (periodic table)Computer scienceEmbedded systemRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling Reactions