Sulfur isotopes from the Paleoproterozoic Francevillian Basin record multigenerational pyrite formation, not depositional conditions
Päärn Paiste, David A. Fike, Karen Bakakas Mayika, Mathieu Moussavou, Aivo Lepland, Anthony R. Prave, Tomohiko Sato, Yuichiro Ueno, Yusuke Sawaki, Jocelyn A. Richardson, R. Seth Wood, Clive Jones, Samuel M. Webb, Kalle Kirsimäe
Abstract
Abstract Bulk-rock sulfur isotope data from pyrite in the ~2.1 billion-year sedimentary rocks of the Francevillian Basin, Gabon, have underpinned ideas about initial oxygenation of Earth’s surface environments and eukaryote evolution. Here, we show, using micro-scale analytical methods, that the bulk sulfur isotope record represents progressive diagenetic modification. Our findings indicate no significant change in microbial sulfur cycling processes and seawater sulfate composition throughout that initial phase of atmosphere-ocean oxygenation of Paleoproterozoic time. This offers an alternative view of Earth system evolution during the transition from an anoxic to an oxic state and highlights the need for a judicious reappraisal of conceptual models using sulfur isotope data as primary depositional signals linked to global-scale biogeochemical processes.