Dissecting the effects of water guest adsorption and framework breathing on the AlO<sub>4</sub>(OH)<sub>2</sub> centres of metal–organic framework MIL-53 (Al) by solid state NMR and structural analysis
Alexander E. Khudozhitkov, Sergei S. Arzumanov, Alexander V. Toktarev, Svetlana V. Cherepanova, Anton A. Gabrienko, Daniil I. Kolokolov, Alexander G. Stepanov
Abstract
Al MAS NMR method is sensitive enough to differentiate the effects of pore contractions and water adsorption to Al-sites basing on the changes of the QCC value.
Topics & Concepts
AdsorptionSolid-stateMetal-organic frameworkChemistrySolid-state nuclear magnetic resonancePhysical chemistryMaterials scienceNuclear magnetic resonancePhysicsMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced NMR Techniques and ApplicationsMagnetism in coordination complexes