Rotation, Electric-Field Responses, and Absolute Enantioselection in Chiral Crystals
Rikuto Oiwa, Hiroaki Kusunose
Abstract
The microscopic origin of chirality, possible electric-field induced static rotational lattice deformation, and rotation-field induced electric polarization are investigated. By building up a realistic tight-binding model for the elemental Te crystal in terms of a symmetry-adapted basis, we identify the microscopic origin of the chirality and essential couplings among polar and axial vectors with the same time-reversal properties. Based on this microscopic model, we elucidate quantitatively that an interband process, driven by nearest-neighbor spin-dependent imaginary hopping, is the key factor in the electric-field induced rotation and its inverse response. From the symmetry point of view, these couplings and responses are characteristic and common to any chiral material, leading to a possible experimental approach to achieve absolute enantioselection by simultaneously applied electric and rotation fields, or a magnetic field and electric current, and so on, as a conjugate field of the chirality.