Radical addition-polar termination cascade: efficient strategy for photoredox-neutral-catalysed cyclopropanation and Giese-type reactions of alkenyl <i>N</i>-methyliminodiacetyl boronates
Yongjun Liu, Wenping Luo, Jiali Wu, Yewen Fang, Yan Li, Xiaoping Jin, Li Zhang, Zongyong Zhang, Fenfen Xu, Chan Du
Abstract
Silicate meets boronate: efficient cyclopropanation and Giese-type reactions of alkenyl <italic>N</italic>-methyliminodiacetyl boronates with alkyl silicates have been realized <italic>via</italic> a photoredox-neutral-catalysed radical-polar crossover process.
Topics & Concepts
CyclopropanationChemistryPolarAlkylCascadeRadicalMedicinal chemistryStereochemistryPhotochemistryOrganic chemistryCatalysisPhysicsChromatographyAstronomyCyclopropane Reaction MechanismsRadical Photochemical ReactionsCatalytic C–H Functionalization Methods