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Fluoroindate Glass Co-Doped with Yb3+/Ho3+ as a 2.85 μm Luminescent Source for MID-IR Sensing

Marcin Kochanowicz, Jacek Żmojda, Agata Baranowska, Marta Kuwik, Bartłomiej Starzyk, Magdalena Leśniak, Piotr Miluski, Wojciech A. Pisarski, Joanna Pisarska, Jan Dorosz, Maurizio Ferrari, Dominik Dorosz

2021Sensors19 citationsDOIOpen Access PDF

Abstract

This work reports on the fabrication and analysis of near-infrared and mid-infrared luminescence spectra and their decays in fluoroindate glasses co-doped with Yb3+/Ho3+. The attention has been paid to the analysis of the Yb3+→ Ho3+ energy transfer processed ions in fluoroindate glasses pumped by 976 nm laser diode. The most effective sensitization for 2 μm luminescence has been obtained in glass co-doped with 0.8YbF3/1.6HoF3. Further study in the mid-infrared spectral range (2.85 μm) showed that the maximum emission intensity has been obtained in fluoroindate glass co-doped with 0.1YbF3/1.4HoF3. The obtained efficiency of Yb3+→ Ho3+ energy transfer was calculated to be up to 61% (0.8YbF3/1.6HoF3), which confirms the possibility of obtaining an efficient glass or glass fiber infrared source for a MID-infrared (MID-IR) sensing application.

Topics & Concepts

LuminescenceMaterials scienceInfraredDopingEnergy transferDiodeAnalytical Chemistry (journal)IonLaser diodeOpticsOptoelectronicsChemistryPhysicsOrganic chemistryChromatographyMolecular physicsGlass properties and applicationsLuminescence Properties of Advanced MaterialsSolid State Laser Technologies