Ultrapure single-band red upconversion luminescence in Er<sup>3+</sup> doped sensitizer-rich ytterbium oxide transparent ceramics for solid-state lighting and temperature sensing
Cong Zhang, Yanli Shi, Kailei Lu, Xiuling Wang, Haifeng Yuan, Ruichong Chen, Jianqi Qi, Tien‐Chang Lu
Abstract
Achieving single-band upconversion (UC) is a challenging but rewarding approach to attain optimal performance in diverse applications. In this paper, we successfully achieved single-band red UC luminescence in Yb 2 O 3 : Er transparent ceramics (TCs) through the utilization of a sensitizer-rich design. The Yb 2 O 3 host, which has a maximum host lattice occupancy by Yb 3+ sensitizers, facilitates the utilization of excitation light and enhances energy transfer to activators, resulting in improved UC luminescence. Specifically, by shortening the ionic spacing between sensitizer and activator, the energy back transfer and the cross-relaxation process are promoted, resulting in weakening of green energy level 4 S 3/2 and 2 H 11/2 emission and enhancement of red energy level 4 F 9/2 emission. The prepared Yb 2 O 3 : Er TCs exhibited superior optical properties with in-line transmittance over 80% at 600 nm. Notably, in the 980nm-excited UC spectrum, green emission does not appear, thus Yb 2 O 3 : Er TCs exhibit ultra-pure single band red emission, with CIE coordinates of (0.72, 0.28) and color purity exceeding 99.9%. To the best of our knowledge, this is the first demonstration of pure red UC luminescence in TCs. Furthermore, the luminescent intensity ratio (LIR) technique was utilized to apply this pure red-emitting TCs for temperature sensing. The absolute sensitivity of Yb 2 O 3 : Er TCs was calculated to be 0.319% K -1 at 304 K, which is the highest level of optical thermometry based on 4 F 9/2 levels splitting of Er 3+ known so far. The integration between pure red UC luminescence and temperature sensing performance opens up new possibilities for the development of multi-functional smart windows.