Synthesis and disassembly of an organometallic polymer comprising redox-active Co<sub>4</sub>S<sub>4</sub> clusters and Janus biscarbene linkers
Jonathan H. Gillen, Connor A. Moore, My K. Vuong, Juvairia Shajahan, Mitchell R. Anstey, Jeffrey R. Alston, Christopher Bejger
Abstract
Discrete Co 4 S 4 clusters can be reversibly crosslinked into redox-active frameworks using Janus bis-N-heterocyclic carbene (NHC) ligands.
Topics & Concepts
RedoxChemistryJanusCluster (spacecraft)Ligand (biochemistry)DispersityPolymerGroup 2 organometallic chemistrySolid-stateElectron transferCombinatorial chemistryNanotechnologyPolymer chemistryPhotochemistryMaterials scienceMoleculeOrganic chemistryComputer sciencePhysical chemistryReceptorProgramming languageBiochemistryPolyoxometalates: Synthesis and ApplicationsOrganometallic Complex Synthesis and CatalysisMetal-Organic Frameworks: Synthesis and Applications