Atmospheric Humic‐Like Substances (HULIS) Act as Ice Active Entities
Jie Chen, Zhijun Wu, Xi Zhao, Yujue Wang, Jingchuan Chen, Yan Qiu, Taomou Zong, Haoxuan Chen, B. B. Wang, Peng Lin, Wen Liu, Song Guo, Maosheng Yao, Limin Zeng, Heike Wex, Xiaohong Liu, Min Hu, Shao‐Meng Li
Abstract
Abstract We investigated the ice nucleation activities of humic‐like substances (HULIS), an important component of organic aerosol (OA), derived from atmospheric and biomass burning aerosols, and produced from aqueous‐phase chemical reactions. Respective HULIS can effectively trigger heterogeneous IN under mixed‐phase cloud conditions. HULIS ice active entities (IAE) were aggregates in size between 0.02 and 0.10 μm. At −20°C, the IAE numbers per unit HULIS mass varied from 213 to 8.7 × 10 4 mg −1 . Such results were different than those detected in aquatic humic substances (HS) from previous studies, implying using HS as surrogates may not robustly estimate the IAE concentrations in the real atmosphere. Combining the abundance of atmospheric HULIS with the present results suggests that HULIS could be an important IAE contributor in the atmosphere where other ice nucleating particle species, such as dust and biological particles, are either low in concentration or absent.