Simple conversion of trisodium phosphide, Na<sub>3</sub>P, into silyl- and cyanophosphides and the structure of a terminal silver phosphide
Grégoire Le Corre, Hansjörg Grützmacher
Abstract
P) with chlorosilanes allows for simple derivatization into silyl- and cyano-substituted phosphanide species which were compared with each other. The recently discovered cyano(triphenylsilyl)phosphanide shows unique coordination properties compared to bis(silyl)phosphides.
Topics & Concepts
PhosphideSilylationChemistryTrisodium citrateSimple (philosophy)Inorganic chemistryPhosphorusMaterials scienceCatalysisNuclear chemistryOrganic chemistryPhilosophyEpistemologySynthesis and characterization of novel inorganic/organometallic compoundsOrganometallic Complex Synthesis and CatalysisOrganophosphorus compounds synthesis