Transition-metal-, oxidant- and additive-free multi-component synthesis of alkyl heteroaryl BCPs enabled by visible-light-induced phosphine-catalyzed halogen-atom transfer
Jun Xu, Yu Hong, Ruiyuan Xu, Yuxin Wang, Yirui Guo, Jiabin Shen, Yuxuan Zhao, Wanmei Li
Abstract
This study describes a pioneering visible-light-induced phosphine-catalyzed halogen-atom transfer (XAT) strategy that heralds a new era in the difunctionalization of [1.1.1]propellane.
Topics & Concepts
ChemistryPhosphineHalogenAlkylCatalysisTransition metalAtom (system on chip)Combinatorial chemistryPhotochemistryOrganic chemistryEmbedded systemComputer scienceRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques