Simulation of the cyclic voltammetric response of an outer-sphere redox species with inclusion of electrical double layer structure and ohmic potential drop
Katherine J. Levey, Martin A. Edwards, Henry S. White, Julie V. Macpherson
Abstract
A finite-element model incorporating electrostatics allows simulation of the influence of the interfacial electric double layer structure, ion migration and ohmic potential drop on the voltammetry of a 1e outer-sphere redox system.
Topics & Concepts
Ohmic contactRedoxDrop (telecommunication)Inclusion (mineral)Cyclic voltammetryChemistryElectrochemistryVoltage dropMaterials scienceLayer (electronics)Chemical physicsChemical engineeringNanotechnologyAnalytical Chemistry (journal)Inorganic chemistryThermodynamicsMineralogyElectrodeChromatographyPhysical chemistryCurrent (fluid)PhysicsElectrical engineeringEngineeringElectrochemical Analysis and ApplicationsAnalytical Chemistry and SensorsConducting polymers and applications