Concomitant emergence of circularly polarized luminescence and single-molecule magnet behavior in chiral-at-metal Dy complex
Bahjat El Rez, Jiawen Liu, Virginie Béreau, Carine Duhayon, Yuki Horino, Takayoshi Suzuki, Laurent Coolen, Jean‐Pascal Sutter
Abstract
Circularly polarized luminescence was evidence in solid state for a chiral-at-metal Dy(<sc>iii</sc>) single-molecule magnet. This CPL is opposite for the enantiomers and develops when the relaxation of the magnetization for the Dy becomes slower.
Topics & Concepts
LuminescenceMagnetCircular polarizationMetalMaterials scienceSingle-molecule magnetMoleculeEnantiomerRelaxation (psychology)MagnetizationChirality (physics)Condensed matter physicsCrystallographyChemistryOptoelectronicsMagnetic fieldStereochemistryPhysicsOrganic chemistryNambu–Jona-Lasinio modelChiral symmetry breakingSocial psychologyMetallurgyQuantum mechanicsPsychologyQuarkMagnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications