Delocalized electron effect on single metal sites in ultrathin conjugated microporous polymer nanosheets for boosting CO <sub>2</sub> cycloaddition
Xiaofei Zhang, Haitao Liu, Pengfei An, Yanan Shi, Jianyu Han, Zhongjie Yang, Chang Long, Jun Guo, Shenlong Zhao, Kun Zhao, Huajie Yin, Lirong Zheng, Binhao Zhang, Xiaoping Liu, Lijuan Zhang, Guodong Li, Zhiyong Tang
Abstract
cycloaddition with different epoxides, single cobalt active sites on the ultrathin CMP nanosheets exhibit unprecedentedly high activity and excellent stability under mild reaction conditions.
Topics & Concepts
Delocalized electronConjugated microporous polymerConjugated systemCycloadditionBoosting (machine learning)Microporous materialPolymerMaterials scienceMetalOrganic polymerNanotechnologyChemical engineeringChemistryOrganic chemistryComposite materialComputer scienceCatalysisMetallurgyEngineeringMachine learningCarbon dioxide utilization in catalysisCO2 Reduction Techniques and CatalystsCarbon Dioxide Capture Technologies